- Hydrogen Reduction Behavior of NCM-based Lithium-ion Battery Cathode Materials
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So-Yeong Lee, So-Yeon Lee, Dae-Hyeon Lee, Ho-Sang Sohn
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J Powder Mater. 2024;31(2):163-168. Published online April 30, 2024
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DOI: https://doi.org/10.4150/jpm.2024.00017
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 Abstract
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- As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 °C and hydrogen partial pressure above 0.5 atm, Ni and Li2O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H2O, and Li2CO3, with about 0.02 wt% Al as an impurity.
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